Oblivion Game of the Year Deluxe using a 50% off coupon I got during the 2011 Winter Sale
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+1
Tough, first activation was Half-Life Anthology.
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I think the first thing I bought on Steam was Terraria the day it came out, before that I had a couple free to play games, hard to remember though!
How about you guys?
EDIT: So Terraria was actually a gift from a friends account, but I was at his house at the time and I gave him money to buy it, so technically it was my first purchase even though it's listed as a gift, but after that was Magicka
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