I still have a lot that I haven't played, but The Longest Journey tops my point and click list as well. It's currently about 5th in my all time list. Here's my top rated P&C games I have played, roughly in this order:
The Longest Journey
The Whispered World
Edna And Harvey: Harvey's New Eyes
Machinarium
Still Life
Harvester
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Tied for best place for me :
Some others also come close, such as Syberia (1/2) and Resonance.
I know it's many but I assure you, all are masterpieces.
PS: And NO Daedalic games are nowhere near that quality. You get nice visuals yes, but story and characters forgettable, scenario mediocre. Can't compare in the slightest with the best in the genre.
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Personal favourite: Day of the Tentacle
10 Honorable mentions:
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http://www.steamgifts.com/giveaway/c5zfp/red-johnsons-chronicles-12-steam-special-edition
Favorite Point and Click Adventure game? Mine is The Longest Journey - by far. It's also top of my favorite games of all time :P
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