Short answer is No.
You could consider the key gone or if you are feeling generous and willing to trust in man's better nature, then you could consider 1) asking the winner to not share the key, 2) ask winner to unmark key as "Received", 3) ask the winner to agree to a re-roll, 4) create a support ticket asking for a re-roll, 5) present the same key to the re-rolled winner.
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Someone won my GA but already had the DLC. Is it ok if they click received and I make another giveaway with the same key?
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