Single Player:
Half Life - Half Life 2 (Episodes included) By far the best FPS game ever created. - Call of Duty SP games (especially the Modern Warfare story) - Quake 2 - Deus Ex 1 & 3 (2 blew chunks)
Multi-Player
Battlefield series - Quake 2 - Team Fortress Classic - Counter Strike up to 1.6
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Deus Ex, though not a pure FPS. Still the best after all those years.
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What is your best FPS game you played? ;)
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