I got Steam with Football Manager 2010 I think. Was enraged I had to install it. :D Now I have something like 600 games on it. The first game I bought on Steam was Civ4 complete. Which just happens to be my fav game of all time.
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Left 4 Dead Bundle, first game was HL2 Deathmatch and Lost Coast thanks to ATI though.
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Counter Strike: Condition Zero... then I lost my account...
made a comeback with The Orange Box in my current account!
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don't laugh, Farm Frenzy 2
lol, I thought I couldn't get a better game for €5.. boy was I wrong when I learned about the sales
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Probably Skyrim, had been playing on consoles up until that point. Had also played some CS:S, but that had been on internet-café's and such
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I think the first thing I bought on Steam was Terraria the day it came out, before that I had a couple free to play games, hard to remember though!
How about you guys?
EDIT: So Terraria was actually a gift from a friends account, but I was at his house at the time and I gave him money to buy it, so technically it was my first purchase even though it's listed as a gift, but after that was Magicka
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